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Home / Issues / № 2, 2015

Chemical sciences

REACTIONS OF DIPROPILAMINE WITY UNSATURATED SURFACTANTS IN THE MODEL OIL–WATER SYSTEM
Simonian G.S.

INTRODUCTION

Petroleum products are among the most widespread and hazardous contaminants of surface waters. Oil is composed of more than 1000 organic compounds containing carbon, hydrogen, oxygen, sulfur, and nitrogen[1].

The nitrogen-containing petroleum products are generally divide into the nitrogen bases and neutral nitrogen compounds. The basic nitrogen compounds are majorly ternary amines, derivatives of pyridine, quinoline, isoquinoline, and acridine, the aniline derivatives being less common. Noteworthily, amines are not found exclusively in oil, they are formed in the hydrosphere via decomposition of proteins and phospholipids as well as due to direct deamination of amino acids [2]. Petroleum products form a number of various structures in aqueous phase, including the surface films, emulsions (oil-in-water or water-in-oil), petroleum aggregates, suspensions, or in the soluble forms absorbed with sediments and suspensions. The emulsion formation involves surface-active oil components: naphthene and carboxylic acids, resins, asphaltenes, etc [3]. The studies of petroleum products behavior in the hydrosphere has revealed that the oil decomposition is a multi-stage process consisting of a series of physical, chemical, and biological steps [4]. This work aimed to study the reactions of dipropilamine (DPA) with N[tris(hydroxymethyl)methyl]acrylamide (TA) in water and in organic solvents attempting their description in the frame of the “oil–water” model.

 EXPERIMENTAL

TA and DPA (both from Aldrich) were used without further purification. Dimethylformamide DMF, dimethylsulfoxide DMSO, and formamide FA were purified as described in Ref. [5]. The rate of DPA reaction with the TA was measured at 293 K by means of US spectroscopy (Safas-170 instrument). The decay of TA concentration was monitored by measuring absorbance value at λ = 230 respectively.

 

RESULTS AND DISCUSSION

     Variation of the initial concentration of the TA resulted in the variation of colloid properties of the reaction medium as well as in the change of the TA structure [6]. Therefore, the rate order and the rate constant of the reactions of TA with DPA were determined over wide ranges of the initial reactants concentration: [TA]0 = 1 × 10–2–1.5 mol L–1, and [DPA]0 = 1 × 10–2–1.0 mol L–1. The studied reaction obeyed the following rate equation:

W0 = k [TA]0[DPA]0.

In contrast to the TA was soluble in DMF, DMSO, and FA. It was of interest to investigate the solvent effect on the TA + DPA reaction rate (Table 1). The reaction rate in various solvents followed the Н2О > FA > DMSO > DMF series.

Similarly to the earlier studied case of surfaceinactive unsaturated compounds in the reaction with secondary amine [7], the TA + DPA reaction rate constant was well correlated with the solvent electrophilic parameter (ЕТ) [8]:

Table 1.

Rate constant of the TA + DPA reaction in aqueous and organic media at Т = 293 K

Solvent

104kTA + DPA , mol–1Ls–1

ЕТ [8]

Н2О

16

63.1

FA

1.8

56.6

DMSO

0.15

45.0

DMF

0.12

43.8

 

log kTA+DPA = (–9.612 ± 0.444) + (0.107 ± 0.008)ЕТ, r = 0.99418.

   To conclude, the studied reaction between the TA and DPA can serve as a simple model of certain processes occurring in natural hydrosphere systems containing oil. It was shown that the unsaturated compounds micellization reduced their reactivity as compared to that of the molecular forms.



References:
1. Syrkin, A.M. and Movsumzade, E.M., Osnovy khimii nefti i gaza: uchebnoe posobie (Fundamentals of Oil and Gas Chemistry: Textbook), Ufa: UGNTU, 2002.

2. Taube, P.R. and Baranova, A.G., Khimiya i mikrobiologiya vody (Chemistry and Microbiology of Water), Moscow: Vysshaja shkola, 1983.

3. Pozdnyshev, G.N., Stabilizatsiya i razrushenie neftyanykh emul’sii (Stabilization and Destroying the Oil Emulsion), Moscow: Nedra, 1982.

4. Davidov, S.L. and Tarasov, V.I., Neft’ i nefteprodukty v okruzhayushchei srede (Oil and Petroleum Products in the Environment), Moscow: RUDN, 2004.

5. Toroptseva, A.M., Belogorodskaya, K.V., and Bondarenko, V.M., Laboratornyi praktikum po khimii i tekhnologii VMS (Laboratory Workshop on Chemistry and Technology of Macromolecular Compounds), Leningrad: Khimiya, 1972.

6. Simonian, G.S., Arutyunyan, R.S., Akopyan, A.G., and Beyleryan, N.M., Inform. Tekhnol. i Upravl., 2002, no. 2, pp. 115–117.

7. Simonian, G.S. and Beyleryan, N.M., Oxidation Commun., 2003, vol. 26, no. 4, pp. 485–491.

8. Dimroth, K. and Reichardt, C., Liebigs Ann. Chem., 1969, vol. 727, pp. 93–105.



Bibliographic reference

Simonian G.S. REACTIONS OF DIPROPILAMINE WITY UNSATURATED SURFACTANTS IN THE MODEL OIL–WATER SYSTEM. International Journal Of Applied And Fundamental Research. – 2015. – № 2 –
URL: www.science-sd.com/461-24858 (29.03.2024).